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The most extensive section of the collection is represented by several subsections: "Materials on the service activity of Mikhail Muravyov"; "Documents prepared by Mikhail Muravyov (reports, memos, notes…)"; "Mikhail Muravyov and peasant reform (1861-1866)"; "The suppression of the uprising in the North-West region of the Russian Empire (1863-1865)"; "Mikhail Muravyov and geography". Here are presented the documents on the service activity of Mikhail Muravyov, which remained in his personal fund (GA RF. F. 811.) In the collections of state authorities (such as the Department of the Ministry of the Imperial Court of destinies - RSHA F. 515.), committees, commissions and non-governmental organizations, where Mikhail Muravyov worked (RSHA). Some of the documents have been published in scientific works and periodicals. The section includes memories of statesmen of contemporaries of Mikhail Muravyov. One of the subsections describes Mikhail Muravyov as a Vice-Chairman and one of the founders of the Imperial Russian Geographical Society.

This section contains letters of Mikhail Muravyov to D. Bludov, V. Dolgoruky, E. Kankrin and other finance ministers, S. S. Lansky, A. F. Orlov, and also composed by S. D. Sheremetev preface to the publication of correspondence of Mikhail Muravyov. The section also contains letters to Mikhail Muravyov, which senders were h numerous state (V. F. Adlerberg, A. M. Gorchakov, P. A. Valuev, I. I. Vasilchikov, A. A. Zeleny, P. D . Kiselev, E. P. Kovalevsky, D. A. Milutin, V. I. Nazimov, etc.) and public figures, metropolitans, archbishops and bishops of the Russian Orthodox Church, writers, journalists and others.